Some P-H bond substitution derivatives and fluxionality of Cp,Mo,( ,u-H)( ,u-PHPh)( CO),
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چکیده
Reaction of PH,Ph with CpzMoz(CO), (M-MO) results in sequential formation of cp,Mo,(CO),(PHzPh)z and fluxional Cp,Mo,(p-HXP-PHPhXCO&. Proton abstraction from Cp,Mo,(p-HXF-PHPhXC0)4 affords [Cp,Mo,(p-PHPhXCO),lwhile reaction with [Ph$Z’F~l yields fluxional Cp,Mo&HXF-PFPhXCO)g.
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تاریخ انتشار 2001